But I am a little confused if as you said the caliper seemed centred on the disk the other way around.
As am I?
Number 12 is the item, now I may be stupid (the jury's still out on that one) but if it goes as shown above, then all it is doing is making the bolt shorter, as the caliper would be tight to the fork slider.
Where as if it goes the other side of the caliper, it moves the caliper away slightly from the slider by the width of the spacer, and so gives you a way of centering the rotor in the caliper, would this not be the reason for having them available in different sizes?
The problem is, I really don't know where they were originaly, as they were caked in crud, so when I soaked the caliper in cleaner they came loose, but not realising they were there, when I was cleaning the caliper half they fell out, before I saw them

Oh well it can wait untill the weekend now, as it is dark when I get in from work most days, maybe someone who has Brembo calipers on there 65LS will have a look and put us all right.
