Right! There are two locating pins, so the reservoir won't turn unless it's up about 1/4".
What tends to happen (my supposition) is this: when topping up the reservoir, it's very easy to get fluid down the cap screw columns and thus between the reservoir and MC. That causes the corrosion. That, and moisture can get in there anyway - it doesn't take much for aluminum to corrode.
That said, the reservoir has a tit that fits into a receiving hole in the MC, with an oring to prevent fluid leaking out. Corrosion has now built up 'above' that oring, and that's what's preventing removal.
With the MC removed, do what you can to get penetrating oil down through the screw holes, or something to handle aluminum corrosion. With a putty knife you can lever up a corner of the reservoir and wiggle a little. Use a heat gun or hair dryer and put it through several heat/cold cycles - lubricating/de-corroding all the time as well.
It's a fiddly job, but somebody's gotta do it!
Take your time and eventually it'll come free without damaging the plastic.