I used 100LL in my '79 Yamaha XS400, then the '81 R65 .
I never did anything to the R65 for use with avgas .
But the exhaust did smell different .
The use of a somewhat leaded fuel, also did not make any difference in the area of valve recession, my exhaust valves were almost at the failure point at 45,000 miles .
Bob I should have explained myself better.
The obvious difference between 100LL and the stuff more usually sold at garages is the octane rating. The aviation stuff is as I understand it (and certainly in Australia) quoted accord to the RON method.
Also in Australia pump gas octane is also quoted according to the RON method, the most common varieties are:-
Unleaded Petrol (ULP) 91 octane
E10 - which contains up to 10% alcohol and is quoted at between 92 and 94 octane depending on which fuel company blended it and what they blended it with.
"Premium" Unleaded Petrol (PULP) - mostly 95 Octane, but some fuel companies blend slightly differently and quote 98 Octane.
By compression ratio and standard timing, the "best fit" for a stock R65 is 91 octane. You can of course (as you have done) run them on higher octane, but there is no point (unless of course the fuel is free as it was in your case) without altering the ignition to take advantage of the increased knock resistance of the higher octane fuel.
Now I have never done this to any BMW, but back in the early 80s when I was playing with a Kawasaki GPZ1100, running on Aviation fuel (in those days, particularly for military use some real "jungle juice" was available offering up to 120 Octane (and higher). On a dyno, with a knock sensor attached, I found that the ignition could be advanced quite significantly, with a measurable difference in power output. A white paint pen was used to mark the ignition plate with the positions for "super" and "avgas".
I agree that running the R65 on 100LL with no modifications would generally cause no problems, but I do ask if you found your plug life shortened due to lead fouling?
I'll also bet that on a long run, the ends of your exhaust pipes were a nice chalk white colour.
Something we have all forgotten (and young folks never knew) is that in an engine in otherwise good condition, lead used to eventually kill most spark plugs, we have become used to plugs lasting pretty much forever since the advent of unleaded.