Hello,
I've run more than 300 000 km on my 1982 R65.
I was lucky enough not to have any valve fail. But I had valve springs fail on me and, thus, forced dismantling only to find that the valves where shot.
Where I live, it is common wisdom to replace valves (and guides) around 120 000 km.
The valve stem on the R65 are thinner than the other model ones. So that may explain the lower duration ??
If I were you, I will start saving in order to have the money available when the bike reach 100 000 km and, then, plan for the job.
Bear in mind that if you are not the first owner of the bike, the mileage on the clock may not be the real one.. (my bike had 3 different clocks in its life so telling how much km she ran need some calculation... and now, the clock shows 7400 km ;-) ) ....